Open AccessTotal Synthesis of Cyanolide A and Confirmation of Its Absolute Configuration
Author(s) -
Hyoungsu Kim,
Jiyong Hong
Publication year - 2010
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/ol101022z
Subject(s) - chemistry , absolute configuration , absolute (philosophy) , total synthesis , stereochemistry , epistemology , philosophy
The tandem allylic oxidation/oxa-Michael reaction promoted by the gem-disubstituent effect and the 2-methyl-6-nitrobenzoic anhydride (MNBA)-mediated dimerization were explored for the efficient and facile synthesis of cyanolide A.
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