Open AccessExploitation of Cyclopropane Ring-Cleavage Reactions for the Rapid Assembly of Tetracyclic Frameworks Related to Gibberellins
Author(s) -
Martin G. Banwell,
A.T. Phillis,
Anthony C. Willis
Publication year - 2006
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/ol062224d
Subject(s) - gibberellin , cyclopropane , chemistry , biogenesis , stereochemistry , cleavage (geology) , ring (chemistry) , botany , organic chemistry , biochemistry , biology , fracture (geology) , paleontology , gene
[Structure: see text] The readily available hexahydrofluorene 5 has been elaborated over six steps, including three involving cyclopropane ring-cleavage reactions, into compound 12 which incorporates the carbocyclic framework associated with gibberellins.
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