Synthesis and Properties of 9,9-Diarylfluorene-Based Triaryldiamines | Zendy

KenTsung Wong | Zendy; Zi-Jien Wang | Zendy; Yuh-Yih Chien | Zendy; ChienLung Wang | Zendy

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Synthesis and Properties of 9,9-Diarylfluorene-Based Triaryldiamines

Author(s) -

KenTsung Wong,

Zi-Jien Wang,

Yuh-Yih Chien,

ChienLung Wang

Publication year - 2001

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol016051y

Subject(s) - chemistry , triflic acid , amination , combinatorial chemistry , catalysis , linkage (software) , medicinal chemistry , organic chemistry , stereochemistry , biochemistry , gene

[reaction: see text] 9,9-Diaryl-2,7-dibromofluorene was synthesized by a triflic acid promoted Friedel-Crafts reaction. Introduction of diarylamino groups at its C2 and C7 positions by a Pd-catalyzed amination results in the formation of a novel class of triaryldiamines. The 9,9-diaryl substituents at the central linkage play a less important role in the photophyscial properties but affect the oxidation potential and improve the morphological stability of these new triarylamines.

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