Electronic and Structural Characteristics of Zinc-Blende Wurtzite Biphasic Homostructure GaN Nanowires
Author(s) -
Benjamin Jacobs,
Virginia M. Ayres,
Mihail P. Petkov,
Joshua B. Halpern,
Maoqi He,
Andrew Baczewski,
Kaylee McElroy,
M.A. Crimp,
Jiaming Zhang,
Harry Shaw
Publication year - 2007
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/nl062871y
Subject(s) - wurtzite crystal structure , cathodoluminescence , zinc , nanowire , materials science , gallium nitride , transmission electron microscopy , spectroscopy , wide bandgap semiconductor , band gap , crystallography , nanotechnology , optoelectronics , chemistry , physics , metallurgy , layer (electronics) , quantum mechanics , luminescence
We report a new biphasic crystalline wurtzite/zinc-blende homostructure in gallium nitride nanowires. Cathodoluminescence was used to quantitatively measure the wurtzite and zinc-blende band gaps. High-resolution transmission electron microscopy was used to identify distinct wurtzite and zinc-blende crystalline phases within single nanowires through the use of selected area electron diffraction, electron dispersive spectroscopy, electron energy loss spectroscopy, and fast Fourier transform techniques. A mechanism for growth is identified.
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