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Metal-Induced Assembly of a Semiconductor Island Lattice: Ge Truncated Pyramids on Au-Patterned Si
Author(s) -
Jeremy T. Robinson,
J. Alexander Liddle,
Andrew M. Minor,
Velimir Radmilović,
Di Yi,
P. Alex Greaney,
Kim Long,
D. C. Chrzan,
O. D. Dubón
Publication year - 2005
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/nl051719d
Subject(s) - nucleation , quantum dot , germanium , lattice (music) , semiconductor , materials science , condensed matter physics , metal , nanotechnology , surface diffusion , diffusion , self assembly , crystallography , optoelectronics , silicon , chemistry , physics , organic chemistry , adsorption , acoustics , metallurgy , thermodynamics
We report the two-dimensional alignment of semiconductor islands using rudimentary metal patterning to control nucleation and growth. In the Ge on Si system, a square array of submicron Au dots on the Si (001) surface induces the assembly of deposited Ge adatoms into an extensive island lattice. Remarkably, these highly ordered Ge islands form between the patterned Au dots and are characterized by a unique truncated pyramidal shape. A model based on patterned diffusion barriers explains the observed ordering and establishes general criteria for the broader applicability of such a directed assembly process to quantum dot ordering.

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