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Novel Catalysts, Room Temperature, and the Importance of Oxygen for the Synthesis of Single-Walled Carbon Nanotubes
Author(s) -
Mark H. Rümmeli,
E. BorowiakPalen,
Thomas Gemming,
Thomas Pichler,
M. Knupfer,
Martin Kalbác̆,
Lothar Dunsch,
O. Jost,
S. Ravi P. Silva,
W. Pompe,
B. Büchner
Publication year - 2005
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/nl050692v
Subject(s) - nucleation , carbon nanotube , catalysis , materials science , chemical engineering , laser ablation , carbon fibers , nanotechnology , metal , fullerene , chemistry , laser , organic chemistry , composite material , metallurgy , physics , optics , composite number , engineering
In this letter, we show for the first time the use of metal oxides as catalysts in the synthesis of single-walled carbon nanotubes (SWCNTs) using laser ablation. Further, SWCNTs have been synthesized at low temperature (down to room temperature), where their nucleation cannot be explained via fullerene nucleation. The data point to a nucleation mechanism previously not identified, that places a stable oxidized ring as the root cause for the growth of SWCNTs.

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