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Effect of Hydrocarbon Chain Length of Amphiphilic Ruthenium Dyes on Solid-State Dye-Sensitized Photovoltaics
Author(s) -
Lukas SchmidtMende,
Jessica E. Kroeze,
James R. Durrant,
Mohammad Khaja Nazeeruddin,
Michaël Grätzel
Publication year - 2005
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/nl050555y
Subject(s) - ruthenium , photovoltaics , hydrocarbon , amphiphile , solid state , photochemistry , chemical engineering , chain (unit) , dye sensitized solar cell , chemistry , materials science , nanotechnology , organic chemistry , photovoltaic system , copolymer , polymer , catalysis , electrode , ecology , physics , astronomy , electrolyte , engineering , biology
We studied the influence of the hydrophobic hydrocarbon chain length of amphiphilic ruthenium dyes on the device performance in solid-state dye-sensitized solar cells. We found that the dyes with longer hydrocarbon chains gave higher efficiency values when used as a sensitizer in solid-state dye-sensitized solar cells. With increasing chain length, we observed higher currents and open-circuit voltages up to a limiting chain length. We attribute this improvement to the expected larger distance between TiO2 and the hole conductor, which seems to suppress recombination effectively.

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