Formation of Nanostructured Fullerene Interlayer through Accelerated Self-Assembly and Cross-Linking of Trichlorosilane Moieties Leading to Enhanced Efficiency of Photovoltaic Cells

A new cross-linkable fullerene material, bis(2-(trichlorosilyl)propyl)-malonate C60 (TSMC), functionalized with two trichlorosilane groups, was easily synthesized by Pt-catalyzed olefin hydrosilylation. By making use of facile hydrolysis of the trichlorosilyl moieties, TSMC can be spontaneously self-assembled and cross-linked on the TiOx surface by a simple spin-coating processing without the aid of photoirradiation or post-thermal treatments. The rapid formation of self-assembled and cross-linked TSMC (SA-C-TSMC) effectively passivates the residual hydroxyl groups on the TiOx surface. More significantly, the solvent-resistant TSMC network features a nanostructured surface to provide extra charge-generating interfacial area and straight electron transport pathways. The device (ITO/TiOx/SA-C-TSMC/P3HT:PC61BM (1:1, w/w)/PEDOT:PSS/Ag) with this C60 interlayer exhibited an efficiency of 3.9% which greatly outperformed the device without this layer. Furthermore, the strategy can also be effectively applied to ...