Kinetic Separation of Hexane Isomers by Fixed-Bed Adsorption with a Microporous Metal−Organic Framework | Zendy

Patrick S. Bárcia | Zendy; F. Zapata | Zendy; José A. C. Silva | Zendy; Alı́rio E. Rodrigues | Zendy; Banglin Chen | Zendy

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Kinetic Separation of Hexane Isomers by Fixed-Bed Adsorption with a Microporous Metal−Organic Framework

Author(s) -

Patrick S. Bárcia,

F. Zapata,

José A. C. Silva,

Alı́rio E. Rodrigues,

Banglin Chen

Publication year - 2007

Publication title -

the journal of physical chemistry b

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.864

H-Index - 392

eISSN - 1520-6106

pISSN - 1520-5207

DOI - 10.1021/jp0721898

Subject(s) - dabco , hexane , microporous material , octane , sorption , adsorption , metal organic framework , chemistry , kinetic energy , metal , vapours , chemical engineering , materials science , inorganic chemistry , organic chemistry , engineering , physics , quantum mechanics , neuroscience , biology

A three-dimensional microporous metal-organic framework Zn(BDC)(Dabco)0.5 (BDC = 1,4-benzenedicarboxylate, Dabco = 1,4-diazabicyclo [2,2,2]octane), having two types of intersecting pores to encapsulate linear hexane and to block branched hexanes, and thus exhibiting highly selective sorption with respect to n-hexane, has been successfully applied to the kinetic separation of hexane isomers by fixed-bed adsorption.

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