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Effect of Surfactants on the Rate of Growth of an Air Bubble by Rectified Diffusion
Author(s) -
Judy Lee,
Sandra E. Kentish,
Muthupandian Ashokkumar
Publication year - 2005
Publication title -
the journal of physical chemistry b
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.864
H-Index - 392
eISSN - 1520-6106
pISSN - 1520-5207
DOI - 10.1021/jp051758d
Subject(s) - bubble , surface tension , dodecylbenzene , diffusion , pulmonary surfactant , aqueous solution , sodium dodecyl sulfate , materials science , air bubble , sulfonate , sodium , chemical engineering , growth rate , rheology , maximum bubble pressure method , chemistry , analytical chemistry (journal) , chromatography , composite material , thermodynamics , mechanics , organic chemistry , metallurgy , physics , geometry , mathematics , engineering
The rectified diffusion growth of a single air bubble levitated in an acoustic field (frequency = 22.35 kHz) in water and in aqueous solutions containing surfactants (sodium dodecyl sulfate and sodium dodecylbenzene sulfonate) was investigated. As reported by Crum (J. Acoust. Soc. Am. 1980, 68, 203), the presence of surfactants at the bubble/liquid interface enhanced the growth rate of the bubble by rectified diffusion. It is suggested in this paper that in addition to the effect of surfactants on the surface tension and interfacial resistance to mass transfer, the effect of surface rheological properties may also contribute to the cause of the enhancement observed in the bubble growth rate.

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