Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates | Zendy

Gary A. Molander | Zendy; Steven R. Wisniewski | Zendy; Elham EtemadiDavan | Zendy

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Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates

Author(s) -

Gary A. Molander,

Steven R. Wisniewski,

Elham EtemadiDavan

Publication year - 2014

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/jo502260x

Subject(s) - chemistry , potassium , palladium , substitution (logic) , coupling (piping) , catalysis , coupling reaction , medicinal chemistry , organic chemistry , combinatorial chemistry , stereochemistry , metallurgy , materials science , computer science , programming language

Conditions have been developed for the palladium-catalyzed cross-coupling of 3-bromo-2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates. Twenty-seven alkenyl-substituted azaborines have been synthesized through this method, providing access to a family of 2,1-borazaronaphthalenes with alkenyl substitution at the C3 position.

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