Kinetic Resolution in Asymmetric Epoxidation using Iminium Salt Catalysis | Zendy

Philip C. Bulman Page | Zendy; Louise F. Appleby | Zendy; Yohan Chan | Zendy; David P. Day | Zendy; Benjamin R. Buckley | Zendy; Alexandra M. Z. Slawin | Zendy; Steven M. Allin | Zendy; Michael J. McKenzie | Zendy

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Kinetic Resolution in Asymmetric Epoxidation using Iminium Salt Catalysis

Author(s) -

Philip C. Bulman Page,

Louise F. Appleby,

Yohan Chan,

David P. Day,

Benjamin R. Buckley,

Alexandra M. Z. Slawin,

Steven M. Allin,

Michael J. McKenzie

Publication year - 2013

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/jo401345m

Subject(s) - iminium , chemistry , kinetic resolution , catalysis , salt (chemistry) , kinetic energy , resolution (logic) , enantioselective synthesis , organic chemistry , combinatorial chemistry , physics , quantum mechanics , artificial intelligence , computer science

The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.

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