Highly Fluorescent Pyreno[2,1-b]pyrroles: First Syntheses, Crystal Structure, and Intriguing Photophysical Properties | Zendy

S. Selvi | Zendy; ShihChieh Pu | Zendy; YiMing Cheng | Zendy; JimMin Fang | Zendy; PiTai Chou | Zendy

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Highly Fluorescent Pyreno[2,1-b]pyrroles: First Syntheses, Crystal Structure, and Intriguing Photophysical Properties

Author(s) -

S. Selvi,

ShihChieh Pu,

YiMing Cheng,

JimMin Fang,

PiTai Chou

Publication year - 2004

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/jo049192x

Subject(s) - fluorescence , stacking , pyrrole , pyrene , chemistry , crystal structure , crystallography , molecule , photochemistry , crystal (programming language) , stereochemistry , organic chemistry , physics , quantum mechanics , computer science , programming language

A series of pyrrole analogues of benzo[a]pyrene have been synthesized in which pyreno[2,1-b]pyrrole exhibits highly fluorescent properties in solution as well as in crystalline form even possessing strong pi-pi stacking. The pi-stacking-induced fluorescence spectral changes lead to future applications such as molecular recognition feasible upon chemical modification.

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