New Experimental Data and Reference Models for the Viscosity and Density of Squalane
Author(s) -
Kurt A. G. Schmidt,
Doug Pagnutti,
Meghan Curran,
Anil Kumar Singh,
J. P. Martin Trusler,
Geoffrey C. Maitland,
Mark McBride-Wright
Publication year - 2014
Publication title -
journal of chemical and engineering data
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.719
H-Index - 132
eISSN - 1520-5134
pISSN - 0021-9568
DOI - 10.1021/je5008789
Subject(s) - squalane , standard deviation , outlier , viscosity , absolute deviation , linear regression , least absolute deviations , thermodynamics , range (aeronautics) , experimental data , empirical modelling , work (physics) , statistics , regression , mathematics , materials science , chemistry , physics , computer science , simulation , chromatography , composite material
Empirical models for the density and the viscosity of squalane (C30H62; 2,6,10,15,19,23-hexamethyltetracosane) have been developed based on an exhaustive review of the data available in the literature and new experimental density and viscosity measurements carried out as a part of this work. The literature review shows there is a substantial lack of density and viscosity data at high temperature (373 to 473) K and high pressure conditions (pressures up to 200 MPa). These gaps were addressed with new experimental measurements carried out at temperatures of (338 to 473) K and at pressures of (1 to 202.1) MPa. The new data were utilized in the model development to improve the density and viscosity calculation of squalane at all conditions including high temperatures and high pressures. The model presented in this work reproduces the best squalane density and viscosity data available based on a new combined outlier and regression algorithm. The combination of the empirical models and the regression approach r...
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