Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions | Zendy

Tim Krappitz | Zendy; Kristina Jovic | Zendy; Florian Feist | Zendy; Hendrik Frisch | Zendy; Vincent P. Rigoglioso | Zendy; James P. Blinco | Zendy; Andrew J. Boydston | Zendy; Christopher BarnerKowollik | Zendy

Open Access

Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions

Author(s) -

Tim Krappitz,

Kristina Jovic,

Florian Feist,

Hendrik Frisch,

Vincent P. Rigoglioso,

James P. Blinco,

Andrew J. Boydston,

Christopher BarnerKowollik

Publication year - 2019

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.9b09025

Subject(s) - copolymer , monomer , romp , chemistry , polymer chemistry , polymerization , ring opening polymerization , metathesis , ring opening metathesis polymerisation , photopolymer , ring (chemistry) , photochemistry , polymer , organic chemistry

We introduce the hybrid copolymerization of two disparate monomer classes (vinyl monomers and ring-strained cyclic olefins) via living photopolymerization. The living character of the polymerization technique (metal-free photo-ROMP) is demonstrated by consecutive chain-extensions. Further, we propose a mechanism for the copolymerization and analyze the copolymer structure in detail by high-resolution mass spectrometry.

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