Electric-Field-Mediated Reversible Transformation between Supramolecular Networks and Covalent Organic Frameworks | Zendy

ZhenFeng Cai | Zendy; Gaolei Zhan | Zendy; Lakshya Daukiya | Zendy; Samuel Eyley | Zendy; Wim Thielemans | Zendy; Kay Severin | Zendy; Steven De Feyter | Zendy

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Electric-Field-Mediated Reversible Transformation between Supramolecular Networks and Covalent Organic Frameworks

Author(s) -

ZhenFeng Cai,

Gaolei Zhan,

Lakshya Daukiya,

Samuel Eyley,

Wim Thielemans,

Kay Severin,

Steven De Feyter

Publication year - 2019

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.9b05265

Subject(s) - chemistry , supramolecular chemistry , electric field , covalent bond , scanning tunneling microscope , polarity (international relations) , nanotechnology , phase (matter) , phase transition , transformation (genetics) , chemical physics , molecule , organic chemistry , condensed matter physics , biochemistry , physics , materials science , quantum mechanics , gene , cell

By using an oriented electric field in a scanning tunneling microscope, one can locally control the condensation of boronic acids at the liquid/solid interface. The phase transition between self-assembled molecular networks and covalent organic frameworks is controlled by changing the polarity of the applied bias. The electric-field-induced phase transformation is reversible under ambient conditions.

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