Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework | Zendy

Joseph H. Carter | Zendy; Xue Han | Zendy; Florian Moreau | Zendy; Iván da Silva | Zendy; Adam C. Nevin | Zendy; Harry G. W. Godfrey | Zendy; Chiu C. Tang | Zendy; Sihai Yang⧫ | Zendy; Martin Schröder | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework

Author(s) -

Joseph H. Carter,

Xue Han,

Florian Moreau,

Iván da Silva,

Adam C. Nevin,

Harry G. W. Godfrey,

Chiu C. Tang,

Sihai Yang⧫,

Martin Schröder

Publication year - 2018

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.8b08433

Subject(s) - chemistry , zirconium , zirconium dioxide , adsorption , sulfur dioxide , metal organic framework , sulfur , metal , inorganic chemistry , organic chemistry , chemical engineering , engineering

We report a record-high SO 2 adsorption capacity of 12.3 mmol g -1 in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO 2 adsorption in MFM-601 is fully reversible and highly selective over CO 2 and N 2 . The binding domains for adsorbed SO 2 and CO 2 molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research