Probing Dynamic Library of Metal-Oxo Building Blocks with γ-Cyclodextrin | Zendy

Clément Falaise | Zendy; Mhamad Aly Moussawi | Zendy; Sébastien Floquet | Zendy; Pavel A. Abramov⧫ | Zendy; Maxim N. Sokolov⧫ | Zendy; Mohamed Haouas | Zendy; Emmanuel Cadot | Zendy

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Probing Dynamic Library of Metal-Oxo Building Blocks with γ-Cyclodextrin

Author(s) -

Clément Falaise,

Mhamad Aly Moussawi,

Sébastien Floquet,

Pavel A. Abramov⧫,

Maxim N. Sokolov⧫,

Mohamed Haouas,

Emmanuel Cadot

Publication year - 2018

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.8b07525

Subject(s) - chemistry , cyclodextrin , metal , combinatorial chemistry , organic chemistry

Formation of one of the most representative polyoxometalate (POM) archetypes, namely the Lindqvist anion M 6 O 19 2- with M = Mo VI or W VI , was considered as elusive in aqueous solution. Herein, we report on the host-guest stabilization of the M 6 O 19 2- species with M = Mo or W from aqueous solution using γ-cyclodextrin as trapping agent. The adduct {M 6 O 19 @γ-CD} 2- reveals remarkable hydrolytic stability that offers new opportunities for exploring potentialities of molybdates or tungstates in the field of biology and medicine, when combined to CDs as efficient drug carrier/delivery agents.

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