Adaptive Coordination-Driven Supramolecular Syntheses toward New Polymetallic Cu(I) Luminescent Assemblies | Zendy

Sloane Evariste | Zendy; Ali Moustafa Khalil | Zendy; Mehdi Elsayed Moussa | Zendy; Alan KwunWa Chan | Zendy; Eugene YauHin Hong | Zendy; HokLai Wong | Zendy; Boris Le Guennic | Zendy; Guillaume Calvez | Zendy; Karine Costuas | Zendy; Vivian WingWah Yam | Zendy; Christophe Lescop | Zendy

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Adaptive Coordination-Driven Supramolecular Syntheses toward New Polymetallic Cu(I) Luminescent Assemblies

Author(s) -

Sloane Evariste,

Ali Moustafa Khalil,

Mehdi Elsayed Moussa,

Alan KwunWa Chan,

Eugene YauHin Hong,

HokLai Wong,

Boris Le Guennic,

Guillaume Calvez,

Karine Costuas,

Vivian WingWah Yam,

Christophe Lescop

Publication year - 2018

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.8b06901

Subject(s) - chemistry , supramolecular chemistry , luminescence , coordination complex , nanotechnology , combinatorial chemistry , molecule , organic chemistry , metal , optoelectronics , physics , materials science

A thermally activated delayed fluorescence (TADF) tetrametallic Cu(I) metallacycle A behaves as a conformationally adaptive preorganized precursor to afford, through straightforward and rational coordination-driven supramolecular processes, a variety of room-temperature solid-state luminescent polymetallic assemblies. Reacting various cyano-based building blocks with A, a homometallic Cu(I) 1D-helical coordination polymer C and Cu 8 M discrete circular heterobimetallic assemblies D M (M = Ni, Pd, Pt) are obtained. Their luminescence behaviors are studied, revealing notably the crucial impact of the spin-orbit coupling offered by the central M metal center on the photophysical properties of the heterobimetallic D M derivatives.

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