Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides | Zendy

Douglas W. Agnew | Zendy; Ida M. DiMucci | Zendy; Alejandra Arroyave | Zendy; Milan Gembický | Zendy; Curtis E. Moore | Zendy; Samantha N. MacMillan | Zendy; Arnold L. Rheingold | Zendy; Kyle M. Lancaster | Zendy; Joshua S. Figueroa | Zendy

Open Access

Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides

Author(s) -

Douglas W. Agnew,

Ida M. DiMucci,

Alejandra Arroyave,

Milan Gembický,

Curtis E. Moore,

Samantha N. MacMillan,

Arnold L. Rheingold,

Kyle M. Lancaster,

Joshua S. Figueroa

Publication year - 2017

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.7b09569

Subject(s) - chemistry , terphenyl , thermogravimetric analysis , sorption , metal , metal organic framework , adsorption , spectroscopy , transition metal , crystallography , inorganic chemistry , organic chemistry , catalysis , physics , quantum mechanics

A permanently porous, three-dimensional metal-organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNAr Mes2 ] 2 , and the d 10 Ni(0) precursor Ni(COD) 2 , produces a porous metal-organic material featuring tetrahedral [Ni(CNAr Mes2 ) 4 ] n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N 2 -adsorption profile.

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