Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex | Zendy

Seungwoo Hong | Zendy; Xiaoyan Lu | Zendy; YongMin Lee | Zendy; Mi Sook Seo | Zendy; Takehiro Ohta | Zendy; Takashi Ogura | Zendy; Martin Clémancey | Zendy; Pascale Maldivi | Zendy; JeanMarc Latour | Zendy; Ritimukta Sarangi | Zendy; Wonwoo Nam | Zendy

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Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex

Author(s) -

Seungwoo Hong,

Xiaoyan Lu,

YongMin Lee,

Mi Sook Seo,

Takehiro Ohta,

Takashi Ogura,

Martin Clémancey,

Pascale Maldivi,

JeanMarc Latour,

Ritimukta Sarangi,

Wonwoo Nam

Publication year - 2017

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.7b08161

Subject(s) - chemistry , reactivity (psychology) , ligand (biochemistry) , electron transfer , nitrene , macrocyclic ligand , photochemistry , polymer chemistry , medicinal chemistry , ion , organic chemistry , receptor , catalysis , medicine , biochemistry , alternative medicine , pathology

A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [Fe V (NTs)(TAML)] - (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [Fe V (NTs)(TAML +• )] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML +• ). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.

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