Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water
Author(s) -
Morgane Gaydou,
Toni Moragas,
Francisco JuliáHernández,
Rubén Martı́n
Publication year - 2017
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/jacs.7b07637
Subject(s) - chemistry , catalysis , carboxylation , hydride , organic chemistry , combinatorial chemistry , environmental chemistry , hydrogen
A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO 2 o a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks under mild conditions.
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