A Mononuclear Nonheme Iron(V)-Imido Complex | Zendy

Seungwoo Hong | Zendy; Kyle D. Sutherlin | Zendy; Anil Kumar Vardhaman | Zendy; James J. Yan | Zendy; Sora Park | Zendy; YongMin Lee | Zendy; Soojeong Jang | Zendy; Xiaoyan Lu | Zendy; Takehiro Ohta | Zendy; Takashi Ogura | Zendy; Edward I. Solomon | Zendy; Wonwoo Nam | Zendy

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A Mononuclear Nonheme Iron(V)-Imido Complex

Author(s) -

Seungwoo Hong,

Kyle D. Sutherlin,

Anil Kumar Vardhaman,

James J. Yan,

Sora Park,

YongMin Lee,

Soojeong Jang,

Xiaoyan Lu,

Takehiro Ohta,

Takashi Ogura,

Edward I. Solomon,

Wonwoo Nam

Publication year - 2017

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.7b04695

Subject(s) - chemistry , nitrene , reactivity (psychology) , ligand (biochemistry) , peripheral blood mononuclear cell , stereochemistry , polymer chemistry , organic chemistry , receptor , biochemistry , in vitro , medicine , alternative medicine , pathology , catalysis

Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe V (NTs)] - (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) Å, and an Fe-N vibration at 817 cm -1 . The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.

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