Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis | Zendy

Jennifer Morvan | Zendy; François Vermersch | Zendy; Ziyun Zhang | Zendy; Laura Falivene | Zendy; Thomas Vivès | Zendy; Vincent Dorcet | Zendy; Thierry Roisnel | Zendy; Christophe Crévisy | Zendy; Luigi Cavallo | Zendy; Nicolas Vanthuyne | Zendy; Guy Bertrand | Zendy; Rodolphe Jazzar | Zendy; Marc Mauduit | Zendy

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Optically Pure C₁-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis

Author(s) -

Jennifer Morvan,

François Vermersch,

Ziyun Zhang,

Laura Falivene,

Thomas Vivès,

Vincent Dorcet,

Thierry Roisnel,

Christophe Crévisy,

Luigi Cavallo,

Nicolas Vanthuyne,

Guy Bertrand,

Rodolphe Jazzar,

Marc Mauduit

Publication year - 2020

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.0c10705

Subject(s) - chemistry , carbene , ruthenium , olefin metathesis , alkyl , metathesis , olefin fiber , acyclic diene metathesis , catalysis , enantioselective synthesis , combinatorial chemistry , stereochemistry , organic chemistry , polymer , polymerization

An expedient access to the first optically pure ruthenium complexes containing C 1 -symmetric cyclic (alkyl)(amino)carbene ligands is reported. They demonstrate excellent catalytic performances in asymmetric olefin metathesis with high enantioselectivities (up to 92% ee). Preliminary mechanistic insights provided by density functional theory models highlight the origin of the enantioselectivity.

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