A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes | Zendy

Oliver P. E. Townrow | Zendy; Cheuk Chung | Zendy; Stuart A. Macgregor | Zendy; Andrew S. Weller | Zendy; José M. Goicoechea | Zendy

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A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

Author(s) -

Oliver P. E. Townrow,

Cheuk Chung,

Stuart A. Macgregor,

Andrew S. Weller,

José M. Goicoechea

Publication year - 2020

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.0c09742

Subject(s) - chemistry , cyclooctene , catalysis , homogeneous , cluster (spacecraft) , alkane , 1,5 cyclooctadiene , cyclooctadiene , alkene , organic chemistry , physics , computer science , thermodynamics , programming language

We report on the synthesis of an alkane-soluble Zintl cluster, [η 4 -Ge 9 (Hyp) 3 ]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis -cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.

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