Oxidation of Alkenes by Water with H2 Liberation | Zendy

Shan Tang | Zendy; Yehoshoa BenDavid | Zendy; David Milstein | Zendy

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Oxidation of Alkenes by Water with H₂ Liberation

Author(s) -

Shan Tang,

Yehoshoa BenDavid,

David Milstein

Publication year - 2020

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.0c01592

Subject(s) - chemistry , wacker process , catalysis , liberation , environmentally friendly , trifluoromethanesulfonate , alkylphenol , indium , organic chemistry , palladium , ecology , biochemistry , alkyl , in vitro , biology

Oxidation by water with H 2 liberation is highly desirable, as it can serve as an environmentally friendly way for the oxidation of organic compounds. Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst combination of a dearomatized acridine-based PNP-Ru complex and indium(III) triflate. Compared to traditional Wacker-type oxidation, this transformation avoids the use of added chemical oxidants and liberates hydrogen gas as the only byproduct.

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