Open AccessInsertion Polymerization of Acrylate
Author(s) -
Damien Guironnet,
Philipp Roesle,
Thomas Rünzi,
Inigo GöttkerSchnetmann,
Stefan Mecking
Publication year - 2008
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/ja808017n
Subject(s) - chemistry , acrylate , copolymer , methyl acrylate , ethylene , polymer chemistry , polymerization , catalysis , organic chemistry , polymer
Multiple insertions of acrylate in copolymerization with ethylene, and an insertion homo-oligomerization of methyl acrylate were observed for the first time. Key to these findings, and to mechanistic insights reported, are labile-substituted complexes as catalyst precursors.
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