Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis | Zendy

Behnaz Ghaffari | Zendy; Sean Preshlock | Zendy; Donald L. Plattner | Zendy; Richard J. Staples | Zendy; Peter E. Maligres | Zendy; Shane W. Krska | Zendy; Robert E. Maleczka | Zendy; Milton R. Smith | Zendy

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Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis

Author(s) -

Behnaz Ghaffari,

Sean Preshlock,

Donald L. Plattner,

Richard J. Staples,

Peter E. Maligres,

Shane W. Krska,

Robert E. Maleczka,

Milton R. Smith

Publication year - 2014

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja506229s

Subject(s) - chemistry , borylation , silylation , catalysis , denticity , homogeneous catalysis , ligand (biochemistry) , chelation , homogeneous , phosphorus , substrate (aquarium) , combinatorial chemistry , scope (computer science) , organic chemistry , metal , biochemistry , alkyl , receptor , physics , oceanography , computer science , aryl , thermodynamics , programming language , geology

Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.

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