Open AccessDiastereoselective Pt Catalyzed Cycloisomerization of Polyenes to Polycycles
Author(s) -
Michael J. Geier,
Michel R. Gagné
Publication year - 2014
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/ja500656k
Subject(s) - cycloisomerization , chemistry , catalysis , alkene , cascade , ligand (biochemistry) , stereochemistry , medicinal chemistry , organic chemistry , receptor , biochemistry , chromatography
Application of a tridentate NHC containing pincer ligand to Pt catalyzed cascade cyclization reactions has allowed for the catalytic, diastereoselective cycloisomerization of biogenic alkene terminated substrates to the their polycyclic counterparts.
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