Ammonia-Rich High-Temperature Superconducting Intercalates of Iron Selenide Revealed through Time-Resolved in Situ X-ray and Neutron Diffraction | Zendy

Stefan J. Sedlmaier | Zendy; Simon J. Cassidy | Zendy; Russell E. Morris | Zendy; Michael Drakopoulos | Zendy; Christina Reinhard | Zendy; Saul J. Moorhouse | Zendy; Dermot O’Hare | Zendy; Pascal Manuel | Zendy; D. D. Khalyavin | Zendy; Simon J. Clarke | Zendy

Open Access

Ammonia-Rich High-Temperature Superconducting Intercalates of Iron Selenide Revealed through Time-Resolved in Situ X-ray and Neutron Diffraction

Author(s) -

Stefan J. Sedlmaier,

Simon J. Cassidy,

Russell E. Morris,

Michael Drakopoulos,

Christina Reinhard,

Saul J. Moorhouse,

Dermot O’Hare,

Pascal Manuel,

D. D. Khalyavin,

Simon J. Clarke

Publication year - 2013

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja411624q

Subject(s) - chemistry , selenide , ammonia , intercalation (chemistry) , alkali metal , neutron diffraction , desorption , diffraction , inorganic chemistry , ammonia borane , x ray crystallography , in situ , crystallography , selenium , adsorption , crystal structure , catalysis , organic chemistry , optics , physics , hydrogen production

The development of a technique for following in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ray diffraction methods, reveals high-temperature superconducting ammonia-rich intercalates of iron selenide which reversibly absorb and desorb ammonia around ambient temperatures.

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