CO2 Capture by a Rhenium(I) Complex with the Aid of Triethanolamine | Zendy

Tatsuki Morimoto | Zendy; Takuya Nakajima | Zendy; Shuhei Sawa | Zendy; Ryoichi Nakanishi | Zendy; Daisuke Imori | Zendy; Osamu Ishitani | Zendy

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CO₂ Capture by a Rhenium(I) Complex with the Aid of Triethanolamine

Author(s) -

Tatsuki Morimoto,

Takuya Nakajima,

Shuhei Sawa,

Ryoichi Nakanishi,

Daisuke Imori,

Osamu Ishitani

Publication year - 2013

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja409271s

Subject(s) - chemistry , rhenium , triethanolamine , diimine , ligand (biochemistry) , denticity , medicinal chemistry , molecule , dimethylformamide , bipyridine , stereochemistry , inorganic chemistry , crystallography , organic chemistry , crystal structure , catalysis , receptor , analytical chemistry (journal) , biochemistry , solvent

A rhenium(I) tricarbonyl diimine complex with a N,N-dimethylformamide ligand captures one CO2 molecule in the presence of triethanolamine (TEOA), giving fac-[Re(I)(bpy)(CO)3{R2N-CH2CH2O-COO}] (bpy = 2,2'-bipyridine, R = CH2CH2OH). This could be a predominant complex in various photocatalytic CO2 reduction reactions using [Re(I)(N^N)(CO)3X](n+) (N^N = diimine ligand; X = monodentate ligand; n = 0, 1) type complexes in the presence of TEOA.

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