MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification | Zendy

J. Canivet | Zendy; Sónia Aguado | Zendy; Yves Schuurman | Zendy; David Farrusseng | Zendy

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MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

Author(s) -

J. Canivet,

Sónia Aguado,

Yves Schuurman,

David Farrusseng

Publication year - 2013

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja312120x

Subject(s) - chemistry , ethylene , catalysis , selectivity , nickel , mesoporous material , butene , combinatorial chemistry , polymer chemistry , phase (matter) , metal , organic chemistry

The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.

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