Dibenzophosphapentaphenes: Exploiting P Chemistry for Gap Fine-Tuning and Coordination-Driven Assembly of Planar Polycyclic Aromatic Hydrocarbons | Zendy

PierreAntoine Bouit | Zendy; A. Escande | Zendy; Rózsa Szűcs | Zendy; Dénes Szieberth | Zendy; Christophe Lescop | Zendy; László Nyulászi | Zendy; Muriel Hissler | Zendy; Régis Réau | Zendy

Open Access

Dibenzophosphapentaphenes: Exploiting P Chemistry for Gap Fine-Tuning and Coordination-Driven Assembly of Planar Polycyclic Aromatic Hydrocarbons

Author(s) -

PierreAntoine Bouit,

A. Escande,

Rózsa Szűcs,

Dénes Szieberth,

Christophe Lescop,

László Nyulászi,

Muriel Hissler,

Régis Réau

Publication year - 2012

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja300171y

Subject(s) - chemistry , phosphole , moiety , planar , coordination complex , nanotechnology , combinatorial chemistry , organic chemistry , metal , computer graphics (images) , computer science , materials science

A synthetic route to planar P-modified polycylic aromatic hydrocarbons (PAHs) is described. The presence of a reactive σ(3),λ(3)-P moiety within the sp(2)-carbon scaffold allows the preparation of a new family of PAHs displaying tunable optical and redox properties. Their frontier molecular orbitals (MOs) are derived from the corresponding phosphole MOs and show extended conjugation with the entire π framework. The coordination ability of the P center allows the coordination-driven assembly of two molecular PAHs onto a Au(I) ion.

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