Facile Synthesis of Well-Defined Block Copolymers Containing Regioregular Poly(3-hexyl thiophene) via Anionic Macroinitiation Method and Their Self-Assembly Behavior
Author(s) -
ChiAn Dai,
WeiChe Yen,
YiHuan Lee,
Chun-Chi Ho,
WeiFang Su
Publication year - 2007
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/ja0733991
Subject(s) - copolymer , chemistry , polymer chemistry , thiophene , block (permutation group theory) , nanofiber , nanostructure , self assembly , anionic addition polymerization , chemical engineering , polymer , organic chemistry , geometry , mathematics , engineering
P3HT-P2VP block copolymers were synthesized using anionic macroinitiation of a vinyl end-functionalized P3HT. With different block ratio of P2VP to P3HT, the block copolymers exhibit sphere, cylinder, lamellae, and nanofiber nanostructures.
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