“Threading-Followed-by-Swelling”: A New Protocol for Rotaxane Synthesis | Zendy

ChingWei Chiu | Zendy; ChienChen Lai | Zendy; ShengHsien Chiu | Zendy

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“Threading-Followed-by-Swelling”: A New Protocol for Rotaxane Synthesis

Author(s) -

ChingWei Chiu,

ChienChen Lai,

ShengHsien Chiu

Publication year - 2007

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja069362i

Subject(s) - chemistry , rotaxane , threading (protein sequence) , swelling , stereochemistry , crystallography , polymer chemistry , combinatorial chemistry , supramolecular chemistry , biochemistry , chemical engineering , crystal structure , protein structure , engineering

We describe the use of the new “threading-followed-by-swelling” protocol to synthesize molecular rotaxanes by modifying our previously reported “oxygen-deficient” macrocycle/dibenzylammonium ion molecular recognition system and using a cis-1-[(Z)-alk-1‘-enyl]-2-vinylcyclopropane motif as the swellable terminal group.

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