A General Route to Very Small Polymer Particles with Controlled Microstructures
Author(s) -
Vincent Monteil,
Peter Wehrmann,
Stefan Mecking
Publication year - 2005
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/ja0558084
Subject(s) - chemistry , polybutadiene , polymer , microstructure , polymerization , polyethylene , microemulsion , aqueous solution , catalysis , polymer chemistry , tacticity , chemical engineering , copolymer , organic chemistry , crystallography , pulmonary surfactant , biochemistry , engineering
Very small polymer particles of 10-30 nm size with various microstructures (polyethylene, syndiotactic 1,2-polybutadiene, poly(cycloolefins)) are prepared by catalytic polymerization with aqueous catalyst microemulsion.
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