A Functionalized, Deep Cavitand Catalyzes the Aminolysis of a Choline Derivative | Zendy

Arnaud Gissot | Zendy; Julius Rebek | Zendy

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A Functionalized, Deep Cavitand Catalyzes the Aminolysis of a Choline Derivative

Author(s) -

Arnaud Gissot,

Julius Rebek

Publication year - 2004

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja049074r

Subject(s) - aminolysis , chemistry , cavitand , derivative (finance) , substrate (aquarium) , stereochemistry , catalysis , organic chemistry , molecule , supramolecular chemistry , oceanography , financial economics , economics , geology

The aminolysis of choline p-nitrophenyl carbonate is catalyzed with turnover by a deep cavitand bearing an introverted pyridone function. The synergy of action between the recognition of the guest in the binding pocket and the catalytic activity brought to bear by the pyridone is responsible for the high substrate specificity observed.

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