Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions | Zendy

Jared L. Anderson | Zendy; Jie Ding | Zendy; Tom Welton | Zendy; Daniel W. Armstrong | Zendy

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Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions

Author(s) -

Jared L. Anderson,

Jie Ding,

Tom Welton,

Daniel W. Armstrong

Publication year - 2002

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja028156h

Subject(s) - chemistry , solvation , ionic liquid , polarity (international relations) , mass spectrometry , molecule , ionization , solvent , implicit solvation , ionic bonding , chemical physics , computational chemistry , chromatography , ion , organic chemistry , cell , catalysis , biochemistry

Room-temperature ionic liquids (RTILs) are useful in many chemical applications. Recent publications have attempted to determine the polarity of RTILs using empirical solvent polarity scales. The results have indicated that most RTILs have similar polarities. Nevertheless, RTILs are capable of behaving quite differently when used as solvents in organic synthesis, matrixes in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry, liquid-liquid extraction, and as stationary phases in gas chromatography. The work presented in this study uses a linear free energy approach to characterize 17 RTILs on the basis of their distinct multiple solvation interactions with probe solute molecules. This model provides data that can be used to help identify the interactions and properties that are important for specific chemical applications.

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