Open AccessA direct synthesis of hydroxysemperoside deglucoside
Author(s) -
George A. Kraus,
Jeff Thurston
Publication year - 1989
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/ja00208a012
Subject(s) - citation , altmetrics , icon , computer science , social media , reuse , information retrieval , world wide web , engineering , programming language , waste management
A 1 0-step synthesis of hydroxysemperoside deglucoside has been achieved. The key step is an organopalladium-mediated cyclization that produces a highly functionalized oxabicyclooctane. The remaining functional groups are introduced by addition to the exo face of the fused bicyclic system.
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