Determination of tensorial orientation of chemical shift anisotropy interaction by relaxation studies of 2IzSz spin order in solution | Zendy

Wen Tsung. Chang | Zendy; Pei Lein Wang | Zendy; Der Ming. Duh | Zendy; Lian Pin Hwang | Zendy

Open Access

Determination of tensorial orientation of chemical shift anisotropy interaction by relaxation studies of 2IzSz spin order in solution

Author(s) -

Wen Tsung. Chang,

Pei Lein Wang,

Der Ming. Duh,

Lian Pin Hwang

Publication year - 1990

Publication title -

the journal of physical chemistry

Language(s) - English

Resource type - Journals

eISSN - 1541-5740

pISSN - 0022-3654

DOI - 10.1021/j100367a028

Subject(s) - order (exchange) , citation , icon , anisotropy , relaxation (psychology) , orientation (vector space) , computer science , social media , altmetrics , informetrics , condensed matter physics , information retrieval , physics , library science , mathematics , psychology , world wide web , bibliometrics , optics , social psychology , geometry , finance , economics , programming language

The observation of selective conversion of Zeeman order into a two-spin order, e.g., 2I{sub z}S{sub z}, of the C-H moiety is made with a coherence transfer technique for measuring the cross correlation of chemical shift anisotropy and dipole-dipole interactions. The temperature-dependent relaxation profiles of the two-spin order are investigated to examine the effect of spin-rotation interaction, which was neglected in a previous study, and subsequently to determine the tensorial orientation of chemical shift anisotropy interaction. Results show excellent agreement with the study from two-dimensional NMR powder spectra.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research