CH overtones in acetophenone and benzaldehyde: aryl and methyl local modes | Zendy

Tabish Rasheed | Zendy; K. P. B. Moosad | Zendy; V. P. N. Nampoori | Zendy; K. Sathianandan | Zendy

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CH overtones in acetophenone and benzaldehyde: aryl and methyl local modes

Author(s) -

Tabish Rasheed,

K. P. B. Moosad,

V. P. N. Nampoori,

K. Sathianandan

Publication year - 1987

Publication title -

the journal of physical chemistry

Language(s) - English

Resource type - Journals

eISSN - 1541-5740

pISSN - 0022-3654

DOI - 10.1021/j100300a004

Subject(s) - acetophenone , benzaldehyde , aryl , chemistry , medicinal chemistry , organic chemistry , catalysis , alkyl

Even though there is great practical benefit from evidence that ideal theories are reasonable approximations at small separations (10-30 A) where these relations are expected to fail, we should not be lulled into complacency. Why do not we observe major deviations from ideality due to structure of the solvent, finite ion size, correlations, and fluctuations? What is the origin(s) of the short-range repulsion and its decay at large separations? Furthermore, does the exponential form for the close-range repulsion hold at very close proximity? The power-law attraction should overwhelm the repulsion to cause a precipitous collapse. Clearly, stiff-steric interactions must exist which are of ultimate importance

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