Production of NO2 from Photolysis of Peroxyacetyl Nitrate | Zendy

Troy L. Mazely | Zendy; Randall R. Friedl | Zendy; Stanley P. Sander | Zendy

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Production of NO2 from Photolysis of Peroxyacetyl Nitrate

Author(s) -

Troy L. Mazely,

Randall R. Friedl,

Stanley P. Sander

Publication year - 1995

Publication title -

the journal of physical chemistry

Language(s) - English

Resource type - Journals

eISSN - 1541-5740

pISSN - 0022-3654

DOI - 10.1021/j100020a044

Subject(s) - peroxyacetyl nitrate , citation , altmetrics , social media , computer science , information retrieval , world wide web , chemistry , combustion , nox

Peroxyacetyl nitrate (PAN) vapor was photolyzed at 248 nm, and the NO2 photoproduct was detected by laser-induced fluorescence. The quantum yield for the production of NO2 from PAN photolysis was determined by comparison to HNO3 photolysis data taken under identical experimental conditions. The average of data collected over a range of total pressures, precursor concentrations, and buffer gases was 0.83 +/- 0.09 for the NO2 quantum yield, where the statistical uncertainty is 2 standard deviations.

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