Aerobic Oxidation of Alcohols and the Synthesis of Benzoxazoles Catalyzed by a Cuprocupric Coordination Polymer (Cu+-CP) Assisted by TEMPO | Zendy

Xun Feng | Zendy; Chen Xu | Zendy; Zhiqiang Wang | Zendy; SiFu Tang | Zendy; Weijun Fu | Zendy; BaoMing Ji | Zendy; LiYa Wang | Zendy

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Aerobic Oxidation of Alcohols and the Synthesis of Benzoxazoles Catalyzed by a Cuprocupric Coordination Polymer (Cu⁺-CP) Assisted by TEMPO

Author(s) -

Xun Feng,

Chen Xu,

Zhiqiang Wang,

SiFu Tang,

Weijun Fu,

BaoMing Ji,

LiYa Wang

Publication year - 2015

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic502884z

Subject(s) - chemistry , catalysis , phthalic acid , alcohol oxidation , salt (chemistry) , bipyridine , polymer chemistry , polymer , organic chemistry , medicinal chemistry , inorganic chemistry , crystal structure

A Cu(+)-CP based on the tetranuclear unit {[(HSQPA)2Cu4(bipy)4]·2H2O}n·2nH2O has been constructed through Cu(2+) salt, 2-(sulfonylquinlium-8-yloxy)phthalic acid (H3SQPA), and 4,4'-bipyridine (bipy). This Cu(+)-CP combined with 2,2,6,6-tetramethylpiperidine-1-oxyl as the cocatalyst is an effective catalyst for aerobic oxidation of alcohols and the synthesis of benzoxazoles and can be recycled at least four times without losing its catalytic activity.

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