Synthesis and Spectroscopic Characterization of High-Spin Mononuclear Iron(II) p-Semiquinonate Complexes | Zendy

Amanda E. Baum | Zendy; Heaweon Park | Zendy; Sergey V. Lindeman | Zendy; Adam T. Fiedler | Zendy

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Synthesis and Spectroscopic Characterization of High-Spin Mononuclear Iron(II) p-Semiquinonate Complexes

Author(s) -

Amanda E. Baum,

Heaweon Park,

Sergey V. Lindeman,

Adam T. Fiedler

Publication year - 2014

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic502564r

Subject(s) - chemistry , characterization (materials science) , spin (aerodynamics) , crystallography , nanotechnology , materials science , aerospace engineering , engineering

Two mononuclear iron(II) p-semiquinonate (pSQ) complexes have been generated via one-electron reduction of precursor complexes containing a substituted 1,4-naphthoquinone ligand. Detailed spectroscopic and computational analysis confirmed the presence of a coordinated pSQ radical ferromagnetically coupled to the high-spin Fe(II) center. The complexes are intended to model electronic interactions between (semi)quinone and iron cofactors in biology.

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