A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst | Zendy

Manas Sutradhar | Zendy; Marina V. Kirillova | Zendy; M. Fátima C. Guedes da Silva | Zendy; Luísa M. D. R. S. Martins | Zendy; Armando J. L. Pombeiro | Zendy

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A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst

Author(s) -

Manas Sutradhar,

Marina V. Kirillova,

M. Fátima C. Guedes da Silva,

Luísa M. D. R. S. Martins,

Armando J. L. Pombeiro

Publication year - 2012

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic3017062

Subject(s) - chemistry , alkane , catalysis , valence (chemistry) , vanadium , aqueous solution , medicinal chemistry , stereochemistry , organic chemistry

The new hexanuclear mixed-valence vanadium complex [V(3)O(3)(OEt)(ashz)(2)(μ-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H(2)O(2). Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions.

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