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The First {Dy4} Single-Molecule Magnet with a Toroidal Magnetic Moment in the Ground State
Author(s) -
Penghu Guo,
JunLiang Liu,
Zemin Zhang,
Liviu Ungur,
Liviu F. Chibotaru,
JiDong Leng,
Fu-Sheng Guo,
MingLiang Tong
Publication year - 2012
Publication title -
inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 233
eISSN - 1520-510X
pISSN - 0020-1669
DOI - 10.1021/ic202650f
Subject(s) - chemistry , ground state , magnet , toroid , magnetic moment , molecule , moment (physics) , single molecule magnet , condensed matter physics , nuclear magnetic resonance , atomic physics , magnetization , magnetic field , nuclear physics , physics , quantum mechanics , plasma , organic chemistry
A toroidal magnetic moment in the absence of a conventional total magnetic moment was first observed in a novel tetranuclear dysprosium cluster with nonmagnetic ground state. The toroidal state is quite robust with respect to variations of the exchange parameters.

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