Gondola-Shaped Luminescent Tetrarhenium Metallacycles with Crown-Ether-like Multiple Recognition Sites | Zendy

Malaichamy Sathiyendiran | Zendy; Rong-Tang Liao | Zendy; Pounraj Thanasekaran | Zendy; TzuooTsair Luo | Zendy; Natarajan Sathiyamoorthy Venkataramanan | Zendy; GeneHsiang Lee | Zendy; ShieMing Peng | Zendy; KuangLieh Lu | Zendy

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Gondola-Shaped Luminescent Tetrarhenium Metallacycles with Crown-Ether-like Multiple Recognition Sites

Author(s) -

Malaichamy Sathiyendiran,

Rong-Tang Liao,

Pounraj Thanasekaran,

TzuooTsair Luo,

Natarajan Sathiyamoorthy Venkataramanan,

GeneHsiang Lee,

ShieMing Peng,

KuangLieh Lu

Publication year - 2006

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic061886w

Subject(s) - chemistry , crown ether , luminescence , ether , molecule , planar , yield (engineering) , metal , bridging (networking) , molecular recognition , crown (dentistry) , ion , stereochemistry , combinatorial chemistry , nanotechnology , organic chemistry , optoelectronics , computer network , physics , computer graphics (images) , materials science , computer science , metallurgy , medicine , dentistry

The self-assembly of gondola-shaped tetrarhenium metallacyclophanes was achieved in near quantitative yield from Re(CO)3 corners, a ditopic heterocyclic clip, and a bischelating-bridging unit using an orthogonal-bonding approach. The highly luminescent metallacycles contain crown-ether-like recognition sites, which are capable of selectively recognizing metal ions and planar aromatic molecules.

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