An Unprecedented Oxidative Migration of a Methyl Group from 2-(2‘,6‘-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium and Osmium | Zendy

Rama Acharyya | Zendy; ShieMing Peng | Zendy; GeneHsiang Lee | Zendy; Samaresh Bhattacharya | Zendy

Open Access

An Unprecedented Oxidative Migration of a Methyl Group from 2-(2‘,6‘-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium and Osmium

Author(s) -

Rama Acharyya,

ShieMing Peng,

GeneHsiang Lee,

Samaresh Bhattacharya

Publication year - 2003

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic034968i

Subject(s) - chemistry , osmium , ruthenium , ring (chemistry) , center (category theory) , medicinal chemistry , group (periodic table) , metal , methyl group , stereochemistry , chemical transformation , organic chemistry , crystallography , catalysis

An unprecedented chemical transformation of 2-(2',6'-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [M(PPh(3))(3)X(2)] (M = Ru, Os; X = Cl, Br) whereby one methyl group from the phenyl ring of the arylazo fragment migrates to the metal center via oxidation to CO.

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