Self-Assembly of Octarhenium-Based Neutral Luminescent Rectangular Prisms | Zendy

Bala. Manimaran | Zendy; Pounraj Thanasekaran | Zendy; T. Rajendran | Zendy; Rong-Tang Liao | Zendy; YenHsiang Liu | Zendy; GeneHsiang Lee | Zendy; ShieMing Peng | Zendy; S. Rajagopal | Zendy; KuangLieh Lu | Zendy

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Self-Assembly of Octarhenium-Based Neutral Luminescent Rectangular Prisms

Author(s) -

Bala. Manimaran,

Pounraj Thanasekaran,

T. Rajendran,

Rong-Tang Liao,

YenHsiang Liu,

GeneHsiang Lee,

ShieMing Peng,

S. Rajagopal,

KuangLieh Lu

Publication year - 2003

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic034172j

Subject(s) - luminescence , rhenium , chemistry , nanoscopic scale , perpendicular , crystallography , nanotechnology , optics , geometry , inorganic chemistry , physics , materials science , mathematics

Self-assembly of rhenium-based nanoscale rectangular prismatic boxes has been achieved in quantitative conversion. The fac-rhenium corner provided three mutually perpendicular coordination sites and served as a good candidate for the construction of 3-D boxes. These are the first Re-based, neutral, luminescent prisms of M(8)L(2)L'(8) type that has been characterized crystallographically. Their luminescent properties and molecular recognition capabilities make these molecular prisms interesting supramolecules.

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