Synthesis and Characterization of Chiral Tetraaza Macrocyclic Nickel(II) and Palladium(II) Complexes | Zendy

Guodong Du | Zendy; Arkady Ellern | Zendy; L. Keith Woo | Zendy

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Synthesis and Characterization of Chiral Tetraaza Macrocyclic Nickel(II) and Palladium(II) Complexes

Author(s) -

Guodong Du,

Arkady Ellern,

L. Keith Woo

Publication year - 2003

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic025818v

Subject(s) - chemistry , palladium , nickel , reactivity (psychology) , ligand (biochemistry) , single crystal , metal , crystal structure , electrophile , mass spectrometry , crystallography , stereochemistry , polymer chemistry , catalysis , organic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology , chromatography

Chiral tetraaza macrocyclic nickel(II) and palladium(II) complexes 2a-e, containing one or two (R,R)-(-)-1,2-cyclohexanediyl bridges, were synthesized by template condensation reactions and characterized by (1)H and (13)C NMR, IR, UV-vis, and mass spectrometry. The electrophilic reactivity of 2a was explored. Crystal structures of Ni complex 2b and metal-free ligand 5 were determined by single-crystal X-ray diffraction.

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